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Issue 4, 2013
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Cross coupling of thioethers with aryl boroxines to construct biarylsvia Rh catalyzed C–S activation

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Abstract

A novel rhodium-catalyzed C–C bond formation was developed to construct biaryls through unreactive aryl C–S bond cleavage of thioethers with aryl boroxines. This protocol provided a supplemental method of traditional Suzuki–Miyaura coupling.

Graphical abstract: Cross coupling of thioethers with aryl boroxines to construct biaryls via Rh catalyzed C–S activation

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Publication details

The article was received on 15 Dec 2012, accepted on 08 Feb 2013 and first published on 11 Feb 2013


Article type: Edge Article
DOI: 10.1039/C3SC22242J
Chem. Sci., 2013,4, 1573-1577

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    Cross coupling of thioethers with aryl boroxines to construct biaryls via Rh catalyzed C–S activation

    F. Pan, H. Wang, P. Shen, J. Zhao and Z. Shi, Chem. Sci., 2013, 4, 1573
    DOI: 10.1039/C3SC22242J

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