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Issue 3, 2012
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Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

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Abstract

Macrolactonization and lactonization viaredox-neutral propargylic CH oxidation of terminal alkynes have been achieved under rhodium-catalyzed conditions, in the presence of the DPEphos ligand.

Graphical abstract: Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

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Publication details

The article was received on 17 Oct 2011, accepted on 24 Nov 2011 and first published on 07 Dec 2011


Article type: Edge Article
DOI: 10.1039/C2SC00812B
Chem. Sci., 2012,3, 789-793

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    Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

    A. Lumbroso, N. Abermil and B. Breit, Chem. Sci., 2012, 3, 789
    DOI: 10.1039/C2SC00812B

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