Jump to main content
Jump to site search

Issue 3, 2012
Previous Article Next Article

BN-substituted diphenylacetylene: a basic model for conjugated π-systems containing the BN bond pair

Author affiliations

Abstract

We report the synthesis, structural characterization, and optoelectronic properties of BN-Tolan 1 and Bis-BN-Tolan 2, one of the simplest conjugated systems containing the BN bond pair. BN-tolans 1 and 2 display absorption and emission properties that are distinct from their carbonaceous analogue, tolan. In addition, Bis-BN-Tolan 2 exhibits unique N–H⋯π(C≡C) hydrogen bonding in the solid state.

Graphical abstract: BN-substituted diphenylacetylene: a basic model for conjugated π-systems containing the BN bond pair

Back to tab navigation

Supplementary files

Article information


Submitted
23 Jul 2011
Accepted
19 Oct 2011
First published
07 Nov 2011

Chem. Sci., 2012,3, 825-829
Article type
Edge Article

BN-substituted diphenylacetylene: a basic model for conjugated π-systems containing the BN bond pair

A. J. V. Marwitz, A. N. Lamm, L. N. Zakharov, M. Vasiliu, D. A. Dixon and S. Liu, Chem. Sci., 2012, 3, 825
DOI: 10.1039/C1SC00500F

Social activity

Search articles by author

Spotlight

Advertisements