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Issue 11, 2011
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A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

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Abstract

1H-Imidazo[4,5-f][1,10]phenanthroline (Hip) can be deprotonated to bridge Zn(II) ions, giving a flexible porous metal azolate framework [Zn7(ip)12](OH)2 (MAF-34) which shows not only drastic structural and luminescent changes for different solvent vapors, but also strong adsorption and quantitative luminescence response for low-pressure CO2.

Graphical abstract: A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

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Publication details

The article was received on 01 Jul 2011, accepted on 04 Aug 2011 and first published on 17 Aug 2011


Article type: Edge Article
DOI: 10.1039/C1SC00421B
Citation: Chem. Sci., 2011,2, 2214-2218

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    A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

    X. Qi, R. Lin, Q. Chen, J. Lin, J. Zhang and X. Chen, Chem. Sci., 2011, 2, 2214
    DOI: 10.1039/C1SC00421B

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