Issue 5, 2010
From the journal:

Chemical Science

Exploiting donor–acceptor interactions in aqueous dynamic combinatorial libraries: exploratory studies of simple systems†

Ho Yu Au-Yeung,a   Fabien B. L. Cougnon,a   Sijbren Otto,b   G. Dan Pantoş*a  and  Jeremy K. M. Sanders*a  

* Corresponding authors

a University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: gdp26@cam.ac.uk, jkms@cam.ac.uk
Fax: +44 (0)1223 336017
Tel: +44 (0)1223 336411

b Centre for Systems Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, Groningen, The Netherlands

Abstract

The behaviour of aqueous dynamic combinatorial libraries (DCLs) containing either electron-rich donor building blocks based on dioxynaphthalene (DN), or electron-deficient acceptor building blocks based on naphthalenediimide (NDI) are described. The influence of concentration and ionic strength on library distribution and diversity, together with the responses to electronically-complementary templates have been explored in detail, establishing the principles to be employed in more complex libraries leading to a new generation of catenanes.

Graphical abstract: Exploiting donor–acceptor interactions in aqueous dynamic combinatorial libraries: exploratory studies of simple systems

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Article information

DOI
https://doi.org/10.1039/C0SC00307G
Article type
Edge Article
Submitted
20 May 2010
Accepted
04 Aug 2010
First published
01 Sep 2010

Chem. Sci., 2010,1, 567-574

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Exploiting donor–acceptor interactions in aqueous dynamic combinatorial libraries: exploratory studies of simple systems

H. Y. Au-Yeung, F. B. L. Cougnon, S. Otto, G. D. Pantoş and J. K. M. Sanders, Chem. Sci., 2010, 1, 567 DOI: 10.1039/C0SC00307G

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