Issue 5, 2004

Substitution reactions at boron atoms in metallacarboranes

Abstract

Data on substitution reactions at boron atoms in 10–12-vertex metallacarboranes, which are of fundamental and applied significance, are generalised. The possible mechanisms of substitution reactions and the influence of the metal fragment on substitution positions in the polyhedron are discussed. The bibliography includes 161 references.

Article information

Article type
Review Article
Submitted
03 Jul 2003

Russ. Chem. Rev., 2004,73, 433-453

Substitution reactions at boron atoms in metallacarboranes

V. I. Bregadze, S. V. Timofeev, I. B. Sivaev and I. A. Lobanova, Russ. Chem. Rev., 2004, 73, 433 DOI: 10.1070/RC2004v073n05ABEH000868

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