Dextran mediated MnFe2O4/ZnS magnetic fluorescence nanocomposites for controlled self-heating properties

Abstract

Dextran mediated MnFe₂O₄/ZnS opto-magnetic nanocomposites with different concentrations of ZnS were competently synthesized adopting the co-precipitation method. The structural, morphological, magnetic, and optical properties of the nanocomposites were exhaustively characterized by XRD, HRTEM, FTIR, VSM techniques, and PL spectroscopy. XRD spectra demonstrate the existence of the cubic spinel phase of MnFe₂O₄ and the cubic zinc blend phase of ZnS in the nanocomposites. HRTEM images show the average crystallite size ranges of 15–21 nm for MnFe₂O₄ and 14–45 nm for ZnS. Investigation of the FTIR spectra reveals the incorporation of ZnS nanoparticles on the surface of MnFe₂O₄ nanoparticles by dint of biocompatible surfactant dextran. The nanocomposites exhibit both magnetic and photoluminescence properties. Photoluminescence analysis confirmed the redshift of the emission peaks owing to the trap states in the ZnS nanocrystals. The room temperature VSM analysis shows that the saturation magnetization and coercivity of MnFe₂O₄ nanoparticles initially increase then decrease with the increasing concentration of ZnS in the nanocomposite. The induction heating analysis shows that the presence of dextran enhances the self heating properties of the MnFe₂O₄/ZnS nanocomposites which can also be controlled by tailoring the concentration of the ZnS nanoparticles. These suggest that MnFe₂O₄/Dex/ZnS is a decent candidate for hyperthermia applications.