Microwave-assisted catalytic conversion of glucose to 5-hydroxymethylfurfural using “three dimensional” graphene oxide hybrid catalysts

Abstract

Hybrids of reduced graphene oxide (rGO) and metal/metal oxide (Pt, NiO/Ni(OH)₂, CoO, Fe₃O₄) nano particle were prepared by reduction of graphene oxide (GO) and metal ion (Pt²⁺, Ni²⁺, Co²⁺, Fe²⁺) hybrids. The M-rGO hybrids (M = Pt, Ni–, Co and Fe) were justified for the transformation of glucose to 5-hydroxymethylfurfural (5-HMF). High glucose → 5-HMF conversion was yielded depending on the nature of the M-rGO catalyst. The Ni-rGO showed the highest 5-HMF yield. The conversion reaction tuned to the optimized state under a microwave-assisted reaction accomplished by using Ni-rGO. In such case, the conversion rate was 99% with a 5-HMF yield of 75%. In order to improve both the conversion and yield, NiGO-FD was prepared by a freeze-dry method. The NiGO-FD remarkably showed the highest conversion of 99% and 5-HMF yield of 95%. Beside the biomass transformation process, the physico-chemical strategy employed herein for multiplying the catalytic efficiency might be justified for catalyzing similar reactions.