Synthesis of dendritic fibrous nanosilica over a cubic core (cSiO2@DFNS) with catalytically efficient silver nanoparticles for reduction of nitroarenes and degradation of organic dyes

Abstract

In this study, dendritic fibrous core–shell silica particles having cubic morphology with uniform and vertical nanochannels have been successfully synthesised. The synthesized dendritic fibrous nanosilica over a cubic core (cSiO₂@DFNS) have been characterized by using various techniques, such as powder X-ray diffraction, TEM, FE-SEM, TGA EDS, FT-IR and N₂ adsorption–desorption experiments. The prepared DFNS particles demonstrated a very high surface area and pore diameter. Amine groups were functionalized on the fibres of cSiO₂@DFNS and after that silver nanoparticles could be successfully immobilized on amine functionalized cubic silica particles. Due to the presence of a high surface area and a uniform pore diameter, the silver nanoparticle loaded cSiO₂@DFNS could be successfully employed as an efficient and recoverable catalyst for reduction of toxic aromatic nitro compounds and degradation of organic dyes. Higher catalytic activity of the prepared material could be attributed to its fibrous morphology which could facilitate proper interactions of the reactants molecules with the silver nanoparticles.