A convenient and efficient precursor transformation route to well-dispersed, stable, and highly accessible supported Au nanocatalysts with excellent catalytic hydrogenation performances

Abstract

A new, convenient, and efficient precursor transformation route for the synthesis of supported Au nanocatalysts was reported. In this strategy, [Au(en)₂]³⁺-riched titanate nanospheres (en: ethylenediamine) with hierarchical flower-like architecture were pre-synthesized via “ammonia etching-ion exchange” processes and then used as the precursors of the objective catalysts. Direct pyrolysis of these precursors, varying in amount of [Au(en)₂]³⁺, led to the formation of Au nanoparticles (AuNPs) with different contents uniformly supported on highly crystalline titania nanoflowers (fTiO₂). The fTiO₂-supported AuNPs nanocomposites possessed highly open porous structures with large surface areas (142.3–149.3 m² g⁻¹), which could allow guest molecules to diffuse in and out easily. More interestingly, the formed AuNPs with small size (∼3.8 nm) were well-dispersed and partially embedded into the nanosheets of fTiO₂, which was beneficial for achieving high activity while avoiding their detachment from the support during application. Accordingly, the AuNPs/TiO₂ catalysts exhibited superior catalytic properties for 4-nitrophenol hydrogenation with significantly higher catalytic efficiencies than many previously reported heterogeneous catalysts. Moreover, the catalytic activity could remain almost unchanged after being recycled several times, demonstrating their high stability. These findings open up a new possibility for rational design and synthesis of supported catalysts for diverse catalytic applications.