Issue 67, 2018, Issue in Progress

Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands

Abstract

Oxidation of vinamidinium salts with meta-chloroperbenzoic acid is the key synthetic step towards new persistent 1,3-di(amino)oxyallyl radical cations. When applied to parent vinamidines, this protocol allows for a simple straightforward synthesis of α-keto-β-diimine ligands, for which no convenient synthesis was previously available.

Graphical abstract: Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands

Supplementary files

Article information

Article type
Paper
Submitted
04 Oct 2018
Accepted
08 Nov 2018
First published
14 Nov 2018
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2018,8, 38346-38350

Metal free oxidation of vinamidine derivatives: a simple synthesis of α-keto-β-diimine ligands

M. Tripathi, V. Regnier, Z. Ziani, M. Devillard, C. Philouze and D. Martin, RSC Adv., 2018, 8, 38346 DOI: 10.1039/C8RA08220K

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements