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Issue 56, 2018, Issue in Progress
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Metal-free hypervalent iodine/TEMPO mediated oxidation of amines and mechanistic insight into the reaction pathways

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Abstract

A highly efficient metal free approach for the oxidation of primary and secondary amines to their corresponding aldehydes and ketones using PhI(OAc)2 in combination with a catalytic amount of TEMPO as an oxidizing agent is described. This protocol is rapid and provides diverse products under milder reaction conditions in excellent yields. In addition, the mechanistic study is well demonstrated by spectroscopic methods.

Graphical abstract: Metal-free hypervalent iodine/TEMPO mediated oxidation of amines and mechanistic insight into the reaction pathways

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Supplementary files

Article information


Submitted
06 Sep 2018
Accepted
08 Sep 2018
First published
14 Sep 2018

This article is Open Access

RSC Adv., 2018,8, 32055-32062
Article type
Paper

Metal-free hypervalent iodine/TEMPO mediated oxidation of amines and mechanistic insight into the reaction pathways

A. H. Bansode and G. Suryavanshi, RSC Adv., 2018, 8, 32055
DOI: 10.1039/C8RA07451H

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