Mesoporous silica nanoparticles with wrinkled structure as the matrix of myristic acid for the preparation of a promising new shape-stabilized phase change material via simple method

Abstract

Wrinkled mesoporous silica nanoparticle (WMSN), with a special and highly uniform morphology, large specific surface area and pore volume, high porosity and radial-like wrinkled channels, was successfully prepared by a simple and easy synthetic method. WMSN was used as the matrix of myristic acid (MA) to prepare a new attractive shape-stabilized PCM (MA/WMSN), and the wrinkled channels of WMSN are useful to prevent the leakage of PCM, and increase the thermal stability and phase change enthalpy of shape-stabilized PCM. Characterizations of MA/WMSN, such as structure, crystallization properties, chemical properties and thermal properties were studied, and the interaction mechanism between the WMSN and MA molecules was elucidated. TGA results suggested that MA/WMSN had excellent thermal stability. When the loading of MA in MA/WMSN was 65%, the melting and crystallizing enthalpies of MA/WSSN were 92.0 J g⁻¹ and 86.0 J g⁻¹, respectively. Additionally, the thermal conductivity of MA/WMSN was 0.37 W mK⁻¹, which was about 1.37 times higher than that of the pure MA. All of the study results demonstrated that MA/WMSN possessed of favourable thermal conductivity, high latent heats and excellent thermal stability, and therefore it could be a suitable thermal energy storage material for practical applications.