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Issue 61, 2018
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Palladium catalyst imbedded in polymers of intrinsic microporosity for the Suzuki–Miyaura coupling reaction

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Abstract

Polymers of intrinsic microporosity (PIMs) are porous polymers with rigid ladder-type chain structures. Synthesizing these polymers usually involves the step polymerization of two types of monomer, namely, active fluorine-substituted aromatic ring monomers and phenolic monomers. Herein, we report a new PIMs preparation method using self-synthesized fluorinated monomers and common monomer 5,5′,6,6′-tetrahydroxy-3,3,3′,3′-tetramethyl spirobisindane. The fluorinated monomers were synthesized through the imidization of tetrafluorophthalic anhydride and aromatic diamines. The resulting PIMs served as a support for palladium, with the formed catalyst showing potential for application in the Suzuki–Miyaura coupling reaction.

Graphical abstract: Palladium catalyst imbedded in polymers of intrinsic microporosity for the Suzuki–Miyaura coupling reaction

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Publication details

The article was received on 23 Jul 2018, accepted on 18 Sep 2018 and first published on 16 Oct 2018


Article type: Paper
DOI: 10.1039/C8RA06214E
Citation: RSC Adv., 2018,8, 35205-35210
  • Open access: Creative Commons BY license
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    Palladium catalyst imbedded in polymers of intrinsic microporosity for the Suzuki–Miyaura coupling reaction

    J. Xu, J. Ou, L. Chen, H. Zhang, S. Ma and M. Ye, RSC Adv., 2018, 8, 35205
    DOI: 10.1039/C8RA06214E

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