Fabrication of Ag3PO4/GO/NiFe2O4 composites with highly efficient and stable visible-light-driven photocatalytic degradation of rhodamine B

Abstract

Effective visible-light-driven Ag₃PO₄/GO/NiFe₂O₄ Z-scheme magnetic composites were successfully fabricated by a simple ion-exchange deposition method. The Ag₃PO₄/GO/NiFe₂O₄ (8%) composite exhibited excellent photocatalytic activity (degradation efficiency was ∼96% within 15 min and kinetic constant reached 0.1956 min⁻¹) and stability when compared to Ag₃PO₄, NiFe₂O₄, and Ag₃PO₄/NiFe₂O₄ for rhodamine B (RhB) degradation. Furthermore, by electrochemical and fluorescence measurements, the Ag₃PO₄/GO/NiFe₂O₄ (8%) material also showed larger transient photocurrent, lower impedance, and longer fluorescence lifetime (7.82 ns). Comparing the activity result dependence with characterization results, it was indicated that photocatalytic activity depended on fast charge transfer from Ag₃PO₄ to NiFe₂O₄ through GO sheet. The h⁺ and ·O₂⁻ species played important roles in RhB degradation under visible-light. A possible Z-scheme mechanism is proposed over the Ag₃PO₄/GO/NiFe₂O₄ (8%) composite. This study might provide a promising visible light responsive photocatalyst for the photocatalytic degradation of organic dyes in wastewater.