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Issue 104, 2016, Issue in Progress
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Transfer hydrodehalogenation of aryl halides accelerated by a saturated sodium acetate aqueous solution

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Abstract

Development of catalytic hydrodehalogenation of halogenated organic compounds is an important topic from the viewpoint of environment protection. Herein, we conducted the first work on the utilization of a saturated aqueous solution of sodium acetate (CH3COONa) as an efficient and environmentally-friendly reaction medium for transfer hydrodehalogenation of various aryl halides using Pd/C as the catalyst. It was found that the transfer hydrodehalogenation could be accelerated significantly by the saturated CH3COONa aqueous solution due to the surfactant-similar effect of CH3COONa and the activation of the C–Cl bond by the dissolved solvated ions.

Graphical abstract: Transfer hydrodehalogenation of aryl halides accelerated by a saturated sodium acetate aqueous solution

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Publication details

The article was received on 02 Oct 2016, accepted on 20 Oct 2016 and first published on 21 Oct 2016


Article type: Communication
DOI: 10.1039/C6RA24559E
RSC Adv., 2016,6, 102193-102197

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    Transfer hydrodehalogenation of aryl halides accelerated by a saturated sodium acetate aqueous solution

    Z. Xue, X. Zhao, J. Wang and T. Mu, RSC Adv., 2016, 6, 102193
    DOI: 10.1039/C6RA24559E

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