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Issue 95, 2016, Issue in Progress
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Supramolecular porous ionic network based on triazinonide and imidazolium: a template-free synthesis of meso-/macroporous organic materials via a one-pot reaction-assembly procedure

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Abstract

A supramolecular porous ionic network (SPIN-1) was designed and prepared using a one-pot procedure, involving the quaternization of triimidazole triazine with cyanuric chloride followed by hydrolysis and in situ assembly. The structure of SPIN-1 was characterized by FT-IR, solid-state 13C CP/TOSS NMR, elemental analysis and XPS. SPIN-1 shows a BET surface area up to 263 m2 g−1 (average pore size 11 nm), and a CO2 capture capacity of 24.7 cm3 g−1, which is competitive for Carbon Capture and Storage (CCS).

Graphical abstract: Supramolecular porous ionic network based on triazinonide and imidazolium: a template-free synthesis of meso-/macroporous organic materials via a one-pot reaction-assembly procedure

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Article information


Submitted
15 Aug 2016
Accepted
19 Sep 2016
First published
20 Sep 2016

RSC Adv., 2016,6, 92443-92448
Article type
Paper

Supramolecular porous ionic network based on triazinonide and imidazolium: a template-free synthesis of meso-/macroporous organic materials via a one-pot reaction-assembly procedure

Z. Hei, G. Song, C. Zhao, W. Fan and M. Huang, RSC Adv., 2016, 6, 92443
DOI: 10.1039/C6RA20590A

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