Issue 74, 2016

NBS-mediated dinitrogen extrusion of diazoacetamides under catalyst-free conditions: practical access to 3-bromooxindole derivatives

Abstract

A synthetically useful transformation arises from NBS-mediated dinitrogen extrusion of N-aryl diazoacetamides under catalyst-free conditions, which gives 3-bromooxindoles in high to excellent yields with high selectivity via a non-carbene process.

Graphical abstract: NBS-mediated dinitrogen extrusion of diazoacetamides under catalyst-free conditions: practical access to 3-bromooxindole derivatives

Supplementary files

Article information

Article type
Communication
Submitted
30 Jun 2016
Accepted
15 Jul 2016
First published
18 Jul 2016

RSC Adv., 2016,6, 70221-70225

NBS-mediated dinitrogen extrusion of diazoacetamides under catalyst-free conditions: practical access to 3-bromooxindole derivatives

X. Wang, K. Dong, B. Yan, C. Zhang, L. Qiu and X. Xu, RSC Adv., 2016, 6, 70221 DOI: 10.1039/C6RA16868J

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