Two unique star-like [MnIVMnIII2LnIII] clusters: magnetic relaxation phenomena

Thomais G. Tziotzi; Milosz Siczek; Tadeusz Lis; Ross Inglis; Constantinos J. Milios

doi:10.1039/C6RA09066D

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Two unique star-like [Mn^IVMn ^III₂Ln^III] clusters: magnetic relaxation phenomena†

Thomais G. Tziotzi,^a Milosz Siczek,^b Tadeusz Lis,^b Ross Inglis*^c and Constantinos J. Milios*^a

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* Corresponding authors

^a Department of Chemistry, University of Crete, Voutes 71003, Herakleion, Greece
E-mail: komil@uoc.gr
Fax: +30-2810-545001
Tel: +30-2810-545099

^b Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland

^c EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, UK
E-mail: r.inglis@ed.ac.uk

Abstract

Employment of H₃L² (=2-(β-naphthalideneamino)-2-hydroxyethyl-1-propanol) in manganese–lanthanide cluster chemistry has led to the isolation of two new isostructural tetrametallic [Mn^III₂Mn^IVLn^III] complexes (Ln = Gd, Dy), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals, thus indicating possible single molecule magnetism behaviour.

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Article information

DOI: https://doi.org/10.1039/C6RA09066D
Article type: Communication
Submitted: 08 Apr 2016
Accepted: 27 Apr 2016
First published: 28 Apr 2016

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RSC Adv., 2016,6, 45326-45329

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Two unique star-like [Mn^IVMn^III₂Ln^III] clusters: magnetic relaxation phenomena

T. G. Tziotzi, M. Siczek, T. Lis, R. Inglis and C. J. Milios, RSC Adv., 2016, 6, 45326 DOI: 10.1039/C6RA09066D

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