Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

Feng Zhao; Bin Li; Huawen Huang; Guo-Jun Deng

doi:10.1039/C5RA26588F

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Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes†

Feng Zhao,^a Bin Li,^a Huawen Huang^a and Guo-Jun Deng*^ab

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* Corresponding authors

^a Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China
E-mail: gjdeng@xtu.edu.cn
Fax: +86-0731-5829-2251
Tel: +86-0731-5829-8601

^b Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Abstract

A palladium-catalyzed construction for N-arylsulfonamide from nitroarenes and arylsulfonyl hydrazides is developed. In this protocol, abundant and stable nitroarenes serve as the nitrogen sources by in situ reduction reaction of hydrogen released from arylsulfonyl hydrazides. No external oxidants or reductants are needed for this kind of transformation.

This article is part of the themed collection: Editors’ collection: Catalytic Organic Transformations

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Article information

DOI: https://doi.org/10.1039/C5RA26588F
Article type: Communication
Submitted: 13 Dec 2015
Accepted: 21 Jan 2016
First published: 26 Jan 2016

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RSC Adv., 2016,6, 13010-13013

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Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

F. Zhao, B. Li, H. Huang and G. Deng, RSC Adv., 2016, 6, 13010 DOI: 10.1039/C5RA26588F

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Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes†

Abstract

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Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

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