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Issue 26, 2016
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Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

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Abstract

Two new polyhedral tolyl-containing metallasiloxanes, {(Na+)2[TolSi(O)O]6(Ni2+)4(Na+)4(OH)2[TolSi(O)O]6}*(EtOH)14(H2O)2 and {[CuSi(O)O]12(Cu2+)4(Na+)4}*(EtOH)8}, and two new large stereoregular cyclosiloxanes, cis-[TolSi(O)OSiMe3]6 and tris-cis-tris-trans-[TolSi(O)OSiMe3]12, have been synthesized and their structures have been determined by X-ray crystallography.

Graphical abstract: Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

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Supplementary files

Article information


Submitted
10 Dec 2015
Accepted
17 Feb 2016
First published
23 Feb 2016

RSC Adv., 2016,6, 22052-22060
Article type
Paper

Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

A. A. Anisimov, Y. N. Kononevich, P. V. Zhemchugov, S. A. Milenin, A. A. Korlyukov, U. S. Tsareva, A. S. Peregudov, P. V. Dorovatovskii, Y. A. Molodtsova, R. U. Takazova, O. I. Shchegolikhina and A. M. Muzafarov, RSC Adv., 2016, 6, 22052
DOI: 10.1039/C5RA26414F

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