Synthesis and diverse general oxidative cyclization catalysis of high-valent MoVIO2(HL) to ubiquitous heterocycles and their chiral analogues with high selectivity

Nabyendu Pramanik; Satinath Sarkar; Dipanwita Roy; Sudipto Debnath; Sukla Ghosh; Saikat Khamarui; Dilip K. Maiti

doi:10.1039/C5RA21825J

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Synthesis and diverse general oxidative cyclization catalysis of high-valent Mo^VIO₂(HL) to ubiquitous heterocycles and their chiral analogues with high selectivity†

Nabyendu Pramanik,^a Satinath Sarkar,^a Dipanwita Roy,^a Sudipto Debnath,^a Sukla Ghosh,^a Saikat Khamarui^a and Dilip K. Maiti*^a

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^a Department of Chemistry, University of Calcutta, 92 A. P. C. Road, Kolkata-700009, India
E-mail: dkmchem@caluniv.ac.in
Fax: +91-33-2351-9755
Tel: +91-33-2350-9937

Abstract

The first synthesis and diverse oxidative cyclization catalysis properties of high-valent Mo^VI–triazole are demonstrated towards highly selective construction of benzimidazoles, benzothiazoles, isoxazolines, isoxazoles and their chiral analogues.

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DOI: https://doi.org/10.1039/C5RA21825J
Article type: Communication
Submitted: 19 Oct 2015
Accepted: 14 Nov 2015
First published: 17 Nov 2015

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RSC Adv., 2015,5, 101959-101964

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Synthesis and diverse general oxidative cyclization catalysis of high-valent Mo^VIO₂(HL) to ubiquitous heterocycles and their chiral analogues with high selectivity

N. Pramanik, S. Sarkar, D. Roy, S. Debnath, S. Ghosh, S. Khamarui and D. K. Maiti, RSC Adv., 2015, 5, 101959 DOI: 10.1039/C5RA21825J

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