Issue 129, 2015
From the journal:

RSC Advances

An Au(iii)–amino alcohol complex for degradation of organophosphorus pesticides†

D. Ferri,a   A. Barba-Bon,ab   A. M. Costero,*ab   P. Gaviña,ab   M. Parraab  and  S. Gilab  

* Corresponding authors

a Instituto Interuniversitario de Reconocimiento Molecular y Desarrollo Tecnológico, Universitat de València, Dr. Moliner, 50, 46100-Burjassot, Valencia, Spain
E-mail: Ana.Costero@uv.es

b CIBER de Bioingeniería Biomateriales y Nanomedicina (CIBER-BBN), Spain

Abstract

An Au(III)–amino alcohol complex has been used to cleave organophosphorous pesticides of the dithiophosphate family. P–S bond breaking was readily demonstrated by 1H NMR, 31P NMR and MS. Thiol fragment release was also demonstrated using 2,4-dinitrobenzenesulfonyl fluorescein ethyl ester as a fluorescent sensor.

Graphical abstract: An Au(iii)–amino alcohol complex for degradation of organophosphorus pesticides

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Article information

DOI
https://doi.org/10.1039/C5RA20645F
Article type
Communication
Submitted
06 Oct 2015
Accepted
04 Dec 2015
First published
07 Dec 2015

RSC Adv., 2015,5, 106941-106944

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An Au(III)–amino alcohol complex for degradation of organophosphorus pesticides

D. Ferri, A. Barba-Bon, A. M. Costero, P. Gaviña, M. Parra and S. Gil, RSC Adv., 2015, 5, 106941 DOI: 10.1039/C5RA20645F

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