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Issue 122, 2015
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Anchorage of a ruthenium complex into modified MOF: synergistic effects for selective oxidation of aromatic and heteroaromatic compounds

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Abstract

The structure of IRMOF-3 was modified with pyridine-2-aldehyde and then the Schiff base moieties were used to anchor ruthenium complex to this metal–organic framework. The prepared catalyst was characterized by X-ray powder diffraction (XRD), diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and FTIR methods. The results show that the prepared catalyst acquires a high potential for selective oxidation of aromatic and heteroaromatic compounds under mild conditions and easy workups.

Graphical abstract: Anchorage of a ruthenium complex into modified MOF: synergistic effects for selective oxidation of aromatic and heteroaromatic compounds

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Supplementary files

Article information


Submitted
06 Sep 2015
Accepted
13 Nov 2015
First published
17 Nov 2015

RSC Adv., 2015,5, 101013-101022
Article type
Paper

Anchorage of a ruthenium complex into modified MOF: synergistic effects for selective oxidation of aromatic and heteroaromatic compounds

K. Tabatabaeian, M. A. Zanjanchi, Nosrat. O. Mahmoodi and T. Eftekhari, RSC Adv., 2015, 5, 101013
DOI: 10.1039/C5RA18179H

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