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Issue 102, 2015
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Synthesis and magnetic properties of nano-dimensional Fe1−xCuxAl2O4 (0.3 ≤ x ≤ 0.8)

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Abstract

Here we report, the sol–gel synthesized, microstructural analysis, surface and magnetic properties of solid solutions of Fe1−xCuxAl2O4. The singular phase of the samples for x values varied between 0.3 and 0.8 at 700 °C has been obtained. The powder X-ray diffraction, electron diffraction and HRTEM analysis reveal that the particle size systemically increases with the increase in x value. The XPS studies have confirmed the presence of Cu2+ species with a (Fe + Cu)/Al surface atomic ratio close to the bulk stoichiometric value. Unlike the common magnetic spinels with B-site magnetic cations, Fe1−xCuxAl2O4 shows only A-site magnetism in a diamond-type lattice. The samples with smaller particle size, namely the samples for x = 0.3 and 0.4 exhibit small magnetization. The origin of such magnetism is attributed to the inversion in the spinel structure and the defect induced magnetism. Except for the x = 0.7 sample, all other samples show spin glass behavior.

Graphical abstract: Synthesis and magnetic properties of nano-dimensional Fe1−xCuxAl2O4 (0.3 ≤ x ≤ 0.8)

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Publication details

The article was received on 23 Jul 2015, accepted on 28 Sep 2015 and first published on 28 Sep 2015


Article type: Paper
DOI: 10.1039/C5RA14623B
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RSC Adv., 2015,5, 83809-83817

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    Synthesis and magnetic properties of nano-dimensional Fe1−xCuxAl2O4 (0.3 ≤ x ≤ 0.8)

    S. Maiti, A. K. Kundu, O. I. Lebedev, P. Bera, C. Anandan, A. Gayen and Md. M. Seikh, RSC Adv., 2015, 5, 83809
    DOI: 10.1039/C5RA14623B

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