Luminescence properties of a novel reddish orange long-lasting phosphorescence phosphor Zn2P2O7:Sm3+,Li+

Abstract

In this article we synthesized a series of new reddish orange long-lasting phosphorescence phosphors by co-doping Li⁺ ions into Sm³⁺ activated α-Zn₂P₂O₇, characterized their luminescence properties, and evaluated the effect of Li⁺ co-doping on both photoluminescence and Phosphorescence. The results showed that both the photoluminescence and Phosphorescence originated from characteristic reddish orange emissions of Sm³⁺ from its 4f–4f transitions of ⁴G_5/2–⁶H_5/2, ⁴G_5/2–⁶H_7/2 ⁴G_5/2–⁶H_9/2 and ⁴G_5/2–⁶H_11/2. Besides markedly enhancing the photoluminescence intensity of Sm³⁺, the Li⁺ entering into the crystal lattice also promoted the long lasting phosphorescence performance via modifying the defect levels in the phosphors. The optimal long afterglow material was achieved when the Li⁺ concentration is 2 mol%. This phosphor shows bright reddish orange phosphorescence which could last for more than 3 hours in the dark. Four peaks appeared in its thermoluminescence curve, and the one at around 350 K was proved to be responsible for the occurrence of long lasting phosphorescence. The release of the captured electrons in the defect levels corresponding to this TL peak in room temperature to emission centers of Sm³⁺ underwent a tunneling process.