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Issue 90, 2015
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An efficient method to prepare a new class of regioregular graft copolymer via a click chemistry approach

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Abstract

Herein, we report the synthesis of a novel regioregular poly-norbornene anhydride-g-(3-hexyl thiophene) (PNBA-g-PHT) graft copolymer. Grignard metathesis polymerization was used to obtain a PHT homopolymer. Then, PHT-N3 was prepared via a chemical modification reaction of the hydroxyl terminated PHT. A click chemistry approach was then used to synthesis MM 1. Finally, ring-opening metathesis polymerization (ROMP) of MM 1 produced the final copolymer. NMR and COSY studies clearly showed that the regioregularity was retained in the newly synthesized copolymer.

Graphical abstract: An efficient method to prepare a new class of regioregular graft copolymer via a click chemistry approach

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Publication details

The article was received on 28 Jun 2015, accepted on 12 Aug 2015 and first published on 13 Aug 2015


Article type: Communication
DOI: 10.1039/C5RA12510C
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RSC Adv., 2015,5, 74159-74161

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    An efficient method to prepare a new class of regioregular graft copolymer via a click chemistry approach

    S. R. Mane, S. Sarkar, V. R. N., A. Sathyan and R. Shunmugam, RSC Adv., 2015, 5, 74159
    DOI: 10.1039/C5RA12510C

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