Issue 74, 2015

A study of oxidizing centers in carbon nanotubes by solid-state NMR

Abstract

Functionalized carbon nanotubes (CNTs) play an important role as catalysts in several oxidation reactions. Active centers, present in a catalyst, are mainly associated with oxidizing functional groups. Therefore, determining the concentration of oxidizing centers from the various functional groups present on the surface of CNTs is very important, but it is yet to be achieved. In the present study, solid-state NMR SSNMR techniques were employed to study the adsorption behavior of trimethylphosphine (TMP) in CNTs using TMP as a probe molecule. The results show that TMP gets oxidized to TMPO (trimethylphosphine oxide). The concentration of oxidizing centers was also selectively measured in the order of sub-mmol per g, employing SSNMR. The oxidizing centers comprise a very small portion among the various functional groups present on the surface of CNTs. The concentration of oxidizing centers was found to increase as the degree of functionalization of CNTs increased. Further studies are required to understand the exact structure of oxidizing centers present in CNTs.

Graphical abstract: A study of oxidizing centers in carbon nanotubes by solid-state NMR

Supplementary files

Article information

Article type
Paper
Submitted
26 Apr 2015
Accepted
06 Jul 2015
First published
07 Jul 2015

RSC Adv., 2015,5, 60380-60385

Author version available

A study of oxidizing centers in carbon nanotubes by solid-state NMR

W. Shen, X. Li and X. Liu, RSC Adv., 2015, 5, 60380 DOI: 10.1039/C5RA07605F

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