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Issue 116, 2015
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Intermolecular OHN hydrogen bond with a proton moving in 3-methylpyridinium 2,6-dichloro-4-nitrophenolate

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Abstract

The neutron structure of 3-methylpyridinium 2,6-dichloro-4-nitrophenolate measured at different temperatures is used to discuss the structural parameters of the OHN intermolecular hydrogen bridges with the proton moving. The experimental and optimized structures, with the precise location of the proton, are used to explain the mechanism of proton transfer in the OHN hydrogen bridge.

Graphical abstract: Intermolecular OHN hydrogen bond with a proton moving in 3-methylpyridinium 2,6-dichloro-4-nitrophenolate

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Publication details

The article was received on 16 Apr 2015, accepted on 02 Nov 2015 and first published on 02 Nov 2015


Article type: Paper
DOI: 10.1039/C5RA06733B
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RSC Adv., 2015,5, 95576-95584

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    Intermolecular OHN hydrogen bond with a proton moving in 3-methylpyridinium 2,6-dichloro-4-nitrophenolate

    I. Majerz and M. J. Gutmann, RSC Adv., 2015, 5, 95576
    DOI: 10.1039/C5RA06733B

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