Cellulosic poly(ionic liquid)s: synthesis, characterization and application in the cycloaddition of CO2 to epoxides

Qin Chen; Chang Peng; Haibo Xie; Zongbao kent Zhao; Ming Bao

doi:10.1039/C5RA05667E

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Cellulosic poly(ionic liquid)s: synthesis, characterization and application in the cycloaddition of CO₂ to epoxides†

Qin Chen,^ab Chang Peng,^b Haibo Xie,*^b Zongbao kent Zhao*^b and Ming Bao^a

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* Corresponding authors

^a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, PR China

^b Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, CAS, Dalian 116023, PR China
E-mail: hbxie@dicp.ac.cn; zhaozb@dicp.ac.cn

Abstract

Cellulosic poly(ionic liquid)s (PILs) were prepared via nucleophilic substitution of chlorinated cellulose by 1-methyl-imidazole and their structure and thermal properties have been fully characterized; the cellulosic PILs were found to be green, efficient and recyclable catalysts for the cycloaddition of CO₂ to epoxides under solvent-free conditions.

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Article information

DOI: https://doi.org/10.1039/C5RA05667E
Article type: Communication
Submitted: 31 Mar 2015
Accepted: 07 May 2015
First published: 08 May 2015

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RSC Adv., 2015,5, 44598-44603

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Cellulosic poly(ionic liquid)s: synthesis, characterization and application in the cycloaddition of CO₂ to epoxides

Q. Chen, C. Peng, H. Xie, Z. K. Zhao and M. Bao, RSC Adv., 2015, 5, 44598 DOI: 10.1039/C5RA05667E

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