Issue 37, 2015
From the journal:

RSC Advances

An approach towards expanding the scope of masked o-benzoquinone dimers to generate diverse compound libraries†‡

Santhosh Kumar Chittimalla,*a   Shoba Laxmi,§b   Amerlyn Chong Ming Liing,§b   Jerald Lam Kai Jun,§b   Rajesh Kuppusamy,a   Sireesha Putturua  and  Chennakesavulu Bandia  

* Corresponding authors

a Medicinal Chemistry Department, AMRI Singapore Research Centre, 61 Science Park Road, #05-01 The Galen, Science Park II, Singapore 117525
E-mail: santhosh.chittimalla@amriglobal.com, chemcsk@gmail.com
Fax: +65-63985511

b School of Chemical & Life Sciences, Singapore Polytechnic, 500 Dover Road, Singapore 139651

Abstract

In this report, a simple and rapid approach for the synthesis of masked o-benzoquinone (MOB) heterodimers is presented. Appropriately substituted 2-methoxyphenols were converted to MOB homodimers which were then transformed to MOB heterodimers utilizing either vinylic substitution (via addition-elimination) reaction protocol or organometallic reaction procedures.

Graphical abstract: An approach towards expanding the scope of masked o-benzoquinone dimers to generate diverse compound libraries

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Article information

DOI
https://doi.org/10.1039/C5RA03627E
Article type
Communication
Submitted
28 Feb 2015
Accepted
19 Mar 2015
First published
25 Mar 2015

RSC Adv., 2015,5, 29391-29396

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An approach towards expanding the scope of masked o-benzoquinone dimers to generate diverse compound libraries

S. K. Chittimalla, S. Laxmi, A. C. Ming Liing, J. L. Kai Jun, R. Kuppusamy, S. Putturu and C. Bandi, RSC Adv., 2015, 5, 29391 DOI: 10.1039/C5RA03627E

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