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Primary thioamides have been utilised directly in water, without any derivatisation, to selectively thioacylate primary amines. By employing 2-hydroxyethylamines, the reaction can be extended to the preparation of 2-thiazolines via formation of β-hydroxythioamides.
U. Pathak, S. Bhattacharyya and S. Mathur, RSC Adv., 2015, 5, 4484 DOI: 10.1039/C4RA13097A
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