Facile and controllable synthesis of carbon-encapsulating carbonate apatite nanowires from biomass containing calcium compounds such as CaC2O4 and CaCO3

Abstract

We report the synthesis of carbon-encapsulating carbonate apatite nanowires through vapor–solid growth by heat-treatment of biomass comprising calcium compounds such as CaC₂O₄ or CaCO₃ at 900 °C using both PH₃ and C₂H₂ as the reactants. The thermal decomposition of CaC₂O₄ or CaCO₃ to CaO with increasing temperature (CaC₂O₄ → CaCO₃ + CO → CaO + CO₂) is the key to achieving the growth of such core–shell nanowires. First, vapor-phase reactions between the gaseous calcium species generated from the derived CaO and gaseous molecules derived from thermal reactions of the reactants (PH₃ and C₂H₂) lead to the oriented growth of core–shell nanowires along the [001] plane. Second, the CO₂ generated during the decomposition of CaCO₃ may be primarily responsible for the incorporation of carbonate ions into the apatite structure. Nanowire growth with knots along the growth direction reveals that our approach is very controllable. Additional demonstrations using kenaf fibers further verify that other types of biomass too are usable.