Development of a novel one-pot synthetic method for the preparation of (Mn0.2Ni0.4Zn0.4Fe2O4)x–(BaFe12O19)1−x nanocomposites and the study of their microwave absorption and magnetic properties

Abstract

The development of a simple yet novel aqueous solution based ‘one-pot’ method has been reported for the preparation of nanocomposites composed of soft ferrite (Mn_0.2Ni_0.4Zn_0.4Fe₂O₄) and hard ferrite (BaFe₁₂O₁₉) phases. A physical mixing method has also been employed to prepare nanocomposites having the same compositions. The effects of synthetic methodologies on the microstructures of the nanocomposites as well as their magnetic and microwave absorption properties have been evaluated. The crystal structures and microstructures of these composites have been investigated using X-ray diffraction, transmission electron microscopy and scanning electron microscopy. In the nanocomposites prepared by both methods, the presence of nanocrystalline Mn_0.2Ni_0.4Zn_0.4Fe₂O₄ and BaFe₁₂O₁₉ phases were detected. However, nanocomposites prepared by the one-pot method possessed better homogeneous distribution of hard and soft ferrite phases than the nanocomposites prepared by the physical mixing method. Very good spring exchange coupling interaction between the hard and soft ferrite phases was observed for the nanocomposites prepared by the one-pot method and these composites exhibited magnetically single phase behaviour. The spring exchange coupling interaction enhanced the magnetic properties (high saturation magnetization and coercivity) and microwave absorption properties of the nanocomposites prepared by the one-pot method, in comparison with the nanocomposites prepared by the physical mixing method as well as pure Mn_0.2Ni_0.4Zn_0.4Fe₂O₄ and BaFe₁₂O₁₉ nanoparticles. The minimum reflection loss of the composites was found to be ∼−25 dB (i.e. >99% absorption) at 8.2 GHz with an absorber thickness of 3.5 mm.