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Issue 73, 2014
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Polymer supported Pd catalyzed carbonylation of aryl bromides for the synthesis of aryl esters and amides

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Abstract

A polymer-anchored palladium(II) catalyst was synthesized and characterized using various spectroscopic techniques. Its catalytic activity was evaluated for the alkoxycarbonylation and aminocarbonylation reactions. These carbonylation reactions were carried out for various substituted aryl bromides using alcohols and amines. Both the reactions were optimized by varying the bases, temperature and solvents. These experiments were carried out under high CO pressure. The catalyst was very stable and can be facilely recovered and reused six times without a significant decrease in its activity and selectivity.

Graphical abstract: Polymer supported Pd catalyzed carbonylation of aryl bromides for the synthesis of aryl esters and amides

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Supplementary files

Article information


Submitted
05 Jun 2014
Accepted
15 Aug 2014
First published
15 Aug 2014

RSC Adv., 2014,4, 38986-38999
Article type
Paper
Author version available

Polymer supported Pd catalyzed carbonylation of aryl bromides for the synthesis of aryl esters and amides

S. M. Islam, K. Ghosh, A. S. Roy and R. A. Molla, RSC Adv., 2014, 4, 38986
DOI: 10.1039/C4RA05365F

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