Issue 44, 2014
From the journal:

RSC Advances

A new site-isolated acid–base bifunctional metal–organic framework for one-pot tandem reaction†

Yu-Ri Lee,a   Young-Min Chung*b  and  Wha-Seung Ahn*a  

* Corresponding authors

a Department of Chemistry and Chemical Engineering, Inha University, Incheon 402-751, Korea
E-mail: whasahn@inha.ac.kr
Tel: +82-32-860-7466

b Department of Nano & Chemical Engineering, Kunsan National University, 558 Daehak-ro, Kunsan, Jeollabuk-Do, Korea
E-mail: ymchung@kunsan.ac.kr
Tel: +82-63-469-4774

Abstract

A highly porous and stable acid–base bifunctional metal–organic framework, MIL-101–NH2–SO3H, was prepared by direct solvothermal synthesis using two mixed (–NO2, –SO3H) terephthalate linkers followed by post-synthesis reduction to the NH2 form, which showed excellent performance for a one-pot tandem deacetalization–nitroaldol reaction.

Graphical abstract: A new site-isolated acid–base bifunctional metal–organic framework for one-pot tandem reaction

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Article information

DOI
https://doi.org/10.1039/C4RA02683G
Article type
Communication
Submitted
27 Mar 2014
Accepted
15 May 2014
First published
15 May 2014

RSC Adv., 2014,4, 23064-23067

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A new site-isolated acid–base bifunctional metal–organic framework for one-pot tandem reaction

Y. Lee, Y. Chung and W. Ahn, RSC Adv., 2014, 4, 23064 DOI: 10.1039/C4RA02683G

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