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Issue 28, 2014
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Intramolecular cyclization–decyclization of new sterically hindered diiminophenol. Synthesis and coordination abilities

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Abstract

The new sterically hindered benzoxazole I was synthesized by the reaction of 3-(2,6-diisopropylphenylimino)butan-2-one and 2-amino-4,6-di-tert-butylphenol. It is shown that compound I is in equilibrium with the open enamine form in solution. The coordination abilities of I have been studied. The ligand I is shown to demonstrate either a neutral coordination type in complex with cadmium iodide or monoanionic type in cadmium complexes obtained by the interaction of I with Me2Cd.

Graphical abstract: Intramolecular cyclization–decyclization of new sterically hindered diiminophenol. Synthesis and coordination abilities

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Supplementary files

Article information


Submitted
16 Dec 2013
Accepted
06 Mar 2014
First published
07 Mar 2014

RSC Adv., 2014,4, 14495-14500
Article type
Paper
Author version available

Intramolecular cyclization–decyclization of new sterically hindered diiminophenol. Synthesis and coordination abilities

G. A. Abakumov, N. O. Druzhkov, E. N. Egorova, T. N. Kocherova, A. S. Shavyrin and A. V. Cherkasov, RSC Adv., 2014, 4, 14495
DOI: 10.1039/C3RA47669C

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