SCHEDULED MAINTENANCE
The first stereoselective vinylation of heterocyclic thiols has been reported. Heterocyclic thiols are shown to react efficiently with activated terminal alkynes in an anti-Markovnikov fashion in absence of any catalyst or additive under microwave irradiation to give Z-selective vinyl sulfides.
N. Rajesh, R. Sarma and D. Prajapati, RSC Adv., 2014, 4, 7834 DOI: 10.1039/C3RA47417H
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