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Issue 15, 2014
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Electrochemical growth and characterization of a p-Cu2O thin film on n-ZnO nanorods for solar cell application

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Abstract

Heterostructural p-Cu2O/n-ZnO solar cells are fabricated by the consecutive electrochemical deposition of an n-ZnO nanorod layer, followed by a p-Cu2O layer on a transparent conductive substrate. The growth parameters, growth temperature and time of applied potential, which determine the crystalline structure and film thickness of Cu2O, are fine-tuned to investigate their effects on the performance of heterojunction solar cells. From XRD and SEM analyses, the best crystalline quality and the optimum Cu2O film thickness are accomplished at the potential of −0.4 V and the growth temperature of 60 °C for 10 min. In addition, the electrolyte concentration plays an important role in the optical absorbance of Cu2O film, which significantly exhibits two-time enhancement as adjusting the CuSO4 concentration of 0.4 M to 0.02 M. The best performance of the heterojunction cell is able to achieve the conversion efficiency of 0.33% with Voc, Jsc, and FF being 0.15 V, 7.03 mA cm−2, and 0.33, respectively. Hence, this study demonstrates that the proposed strategy to improve the solar cell performance realized by electrochemical deposition has the potential to produce cheap and environmentally friendly solar cells.

Graphical abstract: Electrochemical growth and characterization of a p-Cu2O thin film on n-ZnO nanorods for solar cell application

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Article information


Submitted
05 Dec 2013
Accepted
09 Jan 2014
First published
10 Jan 2014

RSC Adv., 2014,4, 7655-7659
Article type
Paper

Electrochemical growth and characterization of a p-Cu2O thin film on n-ZnO nanorods for solar cell application

Y. Hsu, H. Lin, J. Wu, M. Chen, Y. Chen and Y. Lin, RSC Adv., 2014, 4, 7655
DOI: 10.1039/C3RA47188H

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