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Issue 25, 2014
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Threefold and chemoselective couplings of triarylbismuths with benzylic chlorides and iodides using palladium catalysis

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Abstract

This paper describes the palladium-catalyzed studies on threefold coupling of triarylbismuth reagents with benzylic chlorides and iodides. The optimized protocol conditions are operationally simple, delivering threefold coupling of a variety of triarylbismuths in combination with benzylic chlorides and iodides. The two optimized protocols allowed the synthesis of a diverse range of unsymmetrical diarylmethanes in an efficient manner. As part of this study, chemoselective transformation of benzylic chlorides and iodides was also achieved.

Graphical abstract: Threefold and chemoselective couplings of triarylbismuths with benzylic chlorides and iodides using palladium catalysis

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Article information


Submitted
13 Nov 2013
Accepted
27 Jan 2014
First published
07 Mar 2014

RSC Adv., 2014,4, 13134-13144
Article type
Paper

Threefold and chemoselective couplings of triarylbismuths with benzylic chlorides and iodides using palladium catalysis

M. L. N. Rao and R. J. Dhanorkar, RSC Adv., 2014, 4, 13134
DOI: 10.1039/C3RA46672H

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