Issue 43, 2013
From the journal:

RSC Advances

Quantitative evaluation of thermodynamic parameters for thermal back-reaction after mechanically induced fluorescence change†

Fuyuki Ito*a  and  Takehiro Sagawaa  

* Corresponding authors

a Department of Chemistry, Faculty of Education, Shinshu University, 6-ro, Nishinagano, Nagano 380-8544, Japan
E-mail: fito@shinshu-u.ac.jp
Fax: +81-26-238-4114
Tel: +81-26-238-4114

Abstract

Kinetics of the thermal back-reaction of β-diketonate boron difluoride complexes after mechanical perturbation were evaluated by fluorescence intensity changes for the first time, suggesting that the activation parameters of the reaction intermediates governed intermolecular interactions such as hydrogen bonding assisted by substituent groups.

Graphical abstract: Quantitative evaluation of thermodynamic parameters for thermal back-reaction after mechanically induced fluorescence change

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Article information

DOI
https://doi.org/10.1039/C3RA43321H
Article type
Communication
Submitted
01 Jul 2013
Accepted
16 Aug 2013
First published
19 Aug 2013

RSC Adv., 2013,3, 19785-19788

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Quantitative evaluation of thermodynamic parameters for thermal back-reaction after mechanically induced fluorescence change

F. Ito and T. Sagawa, RSC Adv., 2013, 3, 19785 DOI: 10.1039/C3RA43321H

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