Issue 37, 2013
From the journal:

RSC Advances

Oleonin, the first secoiridoid with 1α-configuration from Ligustrum lucidum†

Xiao-Jun Huang,‡abc   Lei Wang,‡ac   Meng Shao,d   Shu-Zhi Hu,a   Ren-Wang Jiang,a   Xin-Sheng Yao,a   Yao-Lan Li,a   Zhi-Qi Yin,*b   Ying Wang*ac  and  Wen-Cai Ye*abc  

* Corresponding authors

a Institute of Traditional Chinese Medicine & Natural Products, College of Pharmacy, Jinan University, Guangzhou 510632, P. R. China
E-mail: chywc@yahoo.com.cn
Fax: 86-20-85221559
Tel: 86-20-85220936

b Department of Phytochemistry, China Pharmaceutical University, Nanjing 210009, P. R. China

c JNU-HKUST Joint Laboratory for Neuroscience & Innovative Drug Research, College of Pharmacy, Jinan University, Guangzhou 510632, P. R. China

d College of Traditional Chinese Medicine, Southern Medical University, Guangzhou 510515, P. R. China

Abstract

The first secoiridoid with unusual 1α-configuration, oleonin (1), was isolated from the fruits of Ligustrum lucidum. The chemical structure and absolute stereochemistry were elucidated on the basis of exhaustive NMR spectral analyses, single crystal X-ray diffraction and quantum chemical CD calculation. The plausible biogenetic pathway of 1 and the evaluation of this mechanism are also described.

Graphical abstract: Oleonin, the first secoiridoid with 1α-configuration from Ligustrum lucidum

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Article information

DOI
https://doi.org/10.1039/C3RA40557E
Article type
Communication
Submitted
31 Jan 2013
Accepted
16 Jul 2013
First published
17 Jul 2013

RSC Adv., 2013,3, 16300-16303

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Oleonin, the first secoiridoid with 1α-configuration from Ligustrum lucidum

X. Huang, L. Wang, M. Shao, S. Hu, R. Jiang, X. Yao, Y. Li, Z. Yin, Y. Wang and W. Ye, RSC Adv., 2013, 3, 16300 DOI: 10.1039/C3RA40557E

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