Issue 18, 2013
From the journal:

RSC Advances

Tetradecanuclear lanthanide-vanadium “nanochocolates”: catalytically-active cationic heteropolyoxovanadium clusters†

Mária Šimuneková,a   Denis Prodius,*bc   Valeriu Mereacre,b   Peter Schwendt,a   Constantin Turta,c   Marco Bettinelli,d   Adolfo Speghini,d   Yanhua Lan,b   Christopher E. Ansonb  and  Annie K. Powell*be  

* Corresponding authors

a Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University, Mlynská dolina, 842 15, Bratislava 4, Slovak Republic

b Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76128 Karlsruhe, Germany
E-mail: annie.powell@kit.edu
Fax: +49-721-608-48142
Tel: +49-721-608-42135

c Institute of Chemistry of the Academy of Sciences of Moldova, The Centre “Physical Chemistry and Nanocompozite”, Academiei str. 3, MD-2028 Chisinau, Republic of Moldova
E-mail: denis.prodius@kit.edu

d Laboratory of Solid State Chemistry, DB, University of Verona, Strada Le Grazie 15, I-37134 Verona, Italy

e Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Abstract

The synthesis, structural characterization, magnetic and catalytic properties of a new class of lanthanide-containing cationic heteropolyoxovanadium clusters with a nanochocolate-like structure are reported. The title compounds were characterized by single-crystal and powder X-ray diffraction, IR and 51V-NMR spectroscopies and magnetic susceptibility measurements.

Graphical abstract: Tetradecanuclear lanthanide-vanadium “nanochocolates”: catalytically-active cationic heteropolyoxovanadium clusters

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Article information

DOI
https://doi.org/10.1039/C3RA40385H
Article type
Communication
Submitted
23 Jan 2013
Accepted
27 Feb 2013
First published
28 Feb 2013

RSC Adv., 2013,3, 6299-6304

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Tetradecanuclear lanthanide-vanadium “nanochocolates”: catalytically-active cationic heteropolyoxovanadium clusters

M. Šimuneková, D. Prodius, V. Mereacre, P. Schwendt, C. Turta, M. Bettinelli, A. Speghini, Y. Lan, C. E. Anson and A. K. Powell, RSC Adv., 2013, 3, 6299 DOI: 10.1039/C3RA40385H

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