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Issue 18, 2013

Direct C-arylation of polyfluoroarenes with diaryliodonium salts via Pd(OAc)2-catalysis

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Abstract

A novel approach towards the Pd-catalyzed arylation of electron-deficient polyfluoroarenes with diaryliodonium salts was developed. The desired fluorinated biaryls were synthesized in good yields. The mechanistic insights involving the PdII/IV catalytic cycle for the present reaction were discussed, which will be helpful in the understanding of catalytic arylations with diaryliodonium salts.

Graphical abstract: Direct C-arylation of polyfluoroarenes with diaryliodonium salts via Pd(OAc)2-catalysis

Supplementary files

Article information


Submitted
26 Nov 2012
Accepted
26 Feb 2013
First published
27 Feb 2013

RSC Adv., 2013,3, 6267-6270
Article type
Communication

Direct C-arylation of polyfluoroarenes with diaryliodonium salts via Pd(OAc)2-catalysis

F. Guo, J. Han, S. Mao, J. Li, X. Geng, J. Yu and L. Wang, RSC Adv., 2013, 3, 6267 DOI: 10.1039/C3RA40374B

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