Issue 14, 2013
From the journal:

RSC Advances

Chiral phosphoric acid catalyzed enantioselective sulfamination of amino-alkenes†

Lijun Li,a   Zequan Li,a   Deshun Huang,a   Haining Wanga  and  Yian Shi*ab  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

b Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States
E-mail: yian@lamar.colostate.edu
Fax: 001-970-4911801
Tel: 001-970-4917424

Abstract

This paper describes a chiral phosphoric acid-catalyzed sulfamination of amino-alkenes to form optically active 2-substituted pyrrolidines and piperidines in up to 86% ee.

Graphical abstract: Chiral phosphoric acid catalyzed enantioselective sulfamination of amino-alkenes

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Article information

DOI
https://doi.org/10.1039/C3RA40307F
Article type
Communication
Submitted
04 Dec 2012
Accepted
01 Feb 2013
First published
01 Feb 2013

RSC Adv., 2013,3, 4523-4525

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Chiral phosphoric acid catalyzed enantioselective sulfamination of amino-alkenes

L. Li, Z. Li, D. Huang, H. Wang and Y. Shi, RSC Adv., 2013, 3, 4523 DOI: 10.1039/C3RA40307F

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