N-type organic semiconductor bisazacoronene diimides efficiently synthesized by a new type of photocyclization involving a Schiff base

Youdi Zhang; Zhenbo Zhao; Xiaomei Huang; Yuanpeng Xie; Chenxi Liu; Jun Li; Xin Guan; Kaichen Zhang; Chuanhui Cheng; Yi Xiao

doi:10.1039/C2RA22488G

N-type organic semiconductor bisazacoronene diimides efficiently synthesized by a new type of photocyclization involving a Schiff base†

Youdi Zhang,^a Zhenbo Zhao,^a Xiaomei Huang,^a Yuanpeng Xie,^a Chenxi Liu,^b Jun Li,^b Xin Guan,^a Kaichen Zhang,^a Chuanhui Cheng*^b and Yi Xiao*^a

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^a State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Rd., Dalian, China
E-mail: xiaoyi@dlut.edu.cn
Fax: +86-411-84986252
Tel: +86-411-84986251

^b School of Physical and Optoelectronic Engineering, Dalian University of Technology, 2 Linggong Rd., Dalian, China
E-mail: cheng_ch79@yahoo.com.cn
Fax: +86-411-84707865
Tel: +86-411-84707865

Abstract

Novel bisazacoronene bisimides (bisaza CBIs) were efficiently synthesized via a new type of photocyclization involving a Schiff base. One of the bisaza CBIs self-assembles into nanobelts and shows reasonable electron mobility in a space-charge-limited current device.

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N-type organic semiconductor bisazacoronene diimides efficiently synthesized by a new type of photocyclization involving a Schiff base†

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N-type organic semiconductor bisazacoronene diimides efficiently synthesized by a new type of photocyclization involving a Schiff base

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