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Issue 20, 2012
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Synthesis and chemistry of a very stable but reactive diisocyanate, trioxabicyclo[3.3.1]nonadiene diisocyanate

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Abstract

The bisdioxine diisocyanate 5 is exceptionally stable, being formed readily in Curtius and Hofmann rearrangements. It does not hydrolyze easily but forms diurea and diurethane derivatives in high yields.

Graphical abstract: Synthesis and chemistry of a very stable but reactive diisocyanate, trioxabicyclo[3.3.1]nonadiene diisocyanate

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Publication details

The article was received on 29 May 2012, accepted on 26 Jun 2012 and first published on 27 Jun 2012


Article type: Paper
DOI: 10.1039/C2RA21073H
RSC Adv., 2012,2, 7743-7746

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    Synthesis and chemistry of a very stable but reactive diisocyanate, trioxabicyclo[3.3.1]nonadiene diisocyanate

    R. Smounig, S. Leber, D. Kvaskoff, G. Kollenz and C. Wentrup, RSC Adv., 2012, 2, 7743
    DOI: 10.1039/C2RA21073H

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