Issue 13, 2012
From the journal:

RSC Advances

Perturbation induced formation of a 3D-network of microcrystals producing soft materials†

David Bardelang,*a   Michel Giorgi,b   Virginie Hornebecq,c   Anatoli Stepanov,d   Egon Rizzato,a   Md. Badruz Zaman,e   Gordon Chan,f   Olivier Ouari*a  and  Paul Tordoa  

* Corresponding authors

a Equipe SREP, Institut de Chimie Radicalaire, ICR, UMR 7273, case 521, Aix-Marseille Université et CNRS, Marseille Cedex 20, Avenue Escadrille Normandie-Niemen, France
E-mail: david.bardelang@univ-amu.fr
Fax: (+33) 491 288 758
Tel: (+33) 491 288 610

b Spectropole, FR 1739, Aix-Marseille Université, Marseille Cedex 20, Avenue Escadrille Normandie-Niemen, France

c Equipe S2P, Laboratoire MADIREL, UMR 7246, Aix-Marseille Université et CNRS, Marseille Cedex 20, Centre de Saint-Jérôme, France

d IM2NP, UMR 6242, Aix-Marseille Université et CNRS, case 142, Avenue Escadrille Normandie-Niemen, France

e Steacie Institute for Molecular Sciences, NRC Canada, 100 Sussex Drive, Ottawa, Ontario K1A0R6 Canada and Center of Excellence for Research in Engineering Materials, Faculty of Engineering, King Saud University, Riyadh, Saudi Arabia

f G. Chan, Institute for Research in Construction, NRC Canada, 1200 Montreal Road, Ontario K1A0R6, Canada

Abstract

Toluene and 1-chloronaphthalene immobilization was observed when perturbing stimuli such as agitation or ultrasound are applied during the cooling of a hot supersaturated solution of the rigid dinitroxide bTbk. X-Ray diffraction and cryo-SEM on gels and solid samples (crystal, powder) confirmed the pivotal role of clathrate type microcrystals in the solvent immobilization process.

Graphical abstract: Perturbation induced formation of a 3D-network of microcrystals producing soft materials

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Article information

DOI
https://doi.org/10.1039/C2RA20208E
Article type
Paper
Submitted
06 Feb 2012
Accepted
12 Apr 2012
First published
13 Apr 2012

RSC Adv., 2012,2, 5605-5609

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Perturbation induced formation of a 3D-network of microcrystals producing soft materials

D. Bardelang, M. Giorgi, V. Hornebecq, A. Stepanov, E. Rizzato, Md. B. Zaman, G. Chan, O. Ouari and P. Tordo, RSC Adv., 2012, 2, 5605 DOI: 10.1039/C2RA20208E

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