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Issue 4, 2011
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Enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes

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Abstract

The enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes with diaryl phosphine oxides is explored for the first time using (S)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine as a catalyst. It afforded 1,4-addition adducts in good to excellent yields with up to 99% ee.

Graphical abstract: Enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes

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Article information


Submitted
03 Jun 2011
Accepted
03 Jun 2011
First published
25 Aug 2011

RSC Adv., 2011,1, 698-705
Article type
Paper

Enantioselective organocatalytic phospha-Michael reaction of α,β-unsaturated aldehydes

X. Luo, Z. Zhou, X. Li, X. Liang and J. Ye, RSC Adv., 2011, 1, 698
DOI: 10.1039/C1RA00269D

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