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Issue 14, 2020
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Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes

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Abstract

Trifluoromethylthiolation-peroxidation of alkenes using AgSCF3 and tert-butyl hydroperoxide has been developed in the presence of a copper catalyst. The method exhibits a broad alkene scope with excellent regio- and chemo-selectivities, providing a variety of β-trifluoromethylthio peroxides from readily available materials. In addition, allenes can be applied to deliver the trifluoromethylthiolation-peroxidation products containing a vinyl-SCF3 moiety.

Graphical abstract: Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes

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Supplementary files

Article information


Submitted
04 May 2020
Accepted
31 May 2020
First published
02 Jun 2020

Org. Chem. Front., 2020,7, 1837-1844
Article type
Research Article

Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes

Y. Chen, Y. Ma, L. Li, M. Cui and Z. Li, Org. Chem. Front., 2020, 7, 1837
DOI: 10.1039/D0QO00533A

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